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  • Документ
    Intumescent fireproof coatintgs based on zeolite-like cement matrices
    (Wiley, 2023-09) Krivenko Pavel; Guzii Sergii; Rudenko Igor; Konstantynovskyi Oleksandr
    Concrete and reinforced concrete building structures (for example, such as tunnels) lose carrying ability in case of high‐temperature fire action. The aim of the research is to study the prevention of reinforced concrete structures (for example, such as tunnels) under fire action in case of using the proposed coating based on the alkaline aluminosilicate binder, which would not consist of organic components dangerous to health. The ratios between constituent oxides in the binder which ensure the ability to bloat the coating under fire action were determined. The performance properties of developed fire protective coating were defined after artificial aging (cycles of alternate drying and cooling) and fire action: bloating factor ‐ 2.0…5.1, adhesion strength ‐ 6.6…8.0 MPa, compressive strength ‐ 2.3…4.5 MPa, cohesive strength of 1.2…1.5 MPa, thermal conductivity coefficient ‐ 0.042…0.066 W/m‐°C, total porosity ‐ 92…97 %. The temperature at which the coating starts to bloat = 200…250 °C has been developed. The results of the test held in the open air suggested drawing a conclusion that with a coating thickness of 6 mm protection of the reinforced concrete from fragile fracture and from plastic deformations in the metal of the reinforcement they provided under fire exposure for a period of 3 hours.
  • Документ
    Corrosion Resistance of Polyester Powder Coatings Using Fillers of Various Chemical Nature
    (2020) Gots, Vladimir; Lastivka, Oles; Berdnyk, Oksana; Tomin, Oleksandr; Shilyuk, Petro
    In the article the effect of fillers of various chemical nature on the corrosion resistance of polyester powder coatings i terms of flaking widths and corrosion expansion widths in accordance with DSTU ISO 4628-8: 2012 was reviewed. According to the results of studies, the effectiveness of the use of fillers to increase the corrosion resistance of the powder coating varies depending on the average particle size and crystalline form of the filler was found. As a rule, in order to receive a powder coating based decorative coating you should apply only one layer of paint, while liquid coatings require applying several layers; this increases the time of coating production. The powder coating can be easily utilized and recycled, thus the economic feasibility of production increases
  • Документ
    Alkaline aluminosilicate binder-based adhesives with increased fire resistance for structural timber elements
    (2019) Krivenko, P. V.; Guzii, S. G.; Bondarenko, O. P.
    The paper presents data on the use of the alkaline aluminosilicate binder-based adhesive of the system Na2O•Al2O3•(4-6)SiO2•(17-20)H2O for gluing and fire protection of structural timber elements. The results of the study of thermoresistant phases in the reaction products of the alkaline aluminosilicates are reported and discussed. The results allowed to show that at SiO2/Al2O3 between 5 and 6 the zeolite-like phases of heulandite types, which, under action of temperatures, are able to form a porous aluminosilicate artificial stone with low thermal conductivity (λ=0.09 Wt/m⋅К, DSTU B V.2.7-105-2000 (GOST 7076-99)) are formed in the reaction products. The use of the developed aluminosilicate adhesives allow for to classify the structural timber elements as hardly burnable and hardly flammable materials (GOST 12.1.044-1989, EN 13823 + A1: 2014-12, ASTM E119-07). They have the following characteristics: water resistance D3 (EN 204:2001), resistance in splitting up 7.8 MPa (GOST 16483.5-1973), adhesion in normal pull-off test up to 2.6 MPa (GOST 32299- 2013 (ISO 4624:2002)).
  • Документ
    Efficiency of Redispersible Polymer Powders in Mortars for Anchoring Application Based on Alkali Activated Portland Cements
    (Trans Tech Publications, 2018) Rudenko, Igor I.; Konstantynovskyi, Oleksandr P.; Kovalchuk, Artem V.; Nikolainko, Marharyta V.; Obremsky, Dmytro V.
    Properties of dry mixes for anchoring application (increasing of mortars strength, adhesion, volume stability etc.) based on alkali activated Portland cement (AAPC) are influenced by different factors. One of them is application of chemical admixtures with different functionality. Adhesive properties are mainly achieved by redispersible polymer powders (RPP). The main problem in choice of RPP’s type is destruction of their molecules with ester links due to alkaline hydrolysis. The purpose of work was investigation of RPP’s molecular structure influence on properties of mortar for anchoring application based on AAPC and determination of the most effective. Efficiency of RPP based on copolymer of versatile acid ester was shown. The application of this RPP provides adhesion of 1.1 MPa and consistency of 190 mm. Positive effect of copolymer of ethylene and vinyl acetate was shown despite of partial destruction of RPP’s molecule as a result of alkaline hydrolysis of vinyl acetate at early terms of hardening. Negative effect of RPP is in decreasing of mortar strength. Thus this problem solving is decreasing of powder content to values which provide necessary physical-mechanical properties (strength, adhesion).