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  • Документ
    Intumescent fireproof coatintgs based on zeolite-like cement matrices
    (Wiley, 2023-09) Krivenko Pavel; Guzii Sergii; Rudenko Igor; Konstantynovskyi Oleksandr
    Concrete and reinforced concrete building structures (for example, such as tunnels) lose carrying ability in case of high‐temperature fire action. The aim of the research is to study the prevention of reinforced concrete structures (for example, such as tunnels) under fire action in case of using the proposed coating based on the alkaline aluminosilicate binder, which would not consist of organic components dangerous to health. The ratios between constituent oxides in the binder which ensure the ability to bloat the coating under fire action were determined. The performance properties of developed fire protective coating were defined after artificial aging (cycles of alternate drying and cooling) and fire action: bloating factor ‐ 2.0…5.1, adhesion strength ‐ 6.6…8.0 MPa, compressive strength ‐ 2.3…4.5 MPa, cohesive strength of 1.2…1.5 MPa, thermal conductivity coefficient ‐ 0.042…0.066 W/m‐°C, total porosity ‐ 92…97 %. The temperature at which the coating starts to bloat = 200…250 °C has been developed. The results of the test held in the open air suggested drawing a conclusion that with a coating thickness of 6 mm protection of the reinforced concrete from fragile fracture and from plastic deformations in the metal of the reinforcement they provided under fire exposure for a period of 3 hours.
  • Документ
    Effect of technological factors on freeze-thaw resistance of alkali-activated slag cement concrete in NaCl solution
    (AIP Publishing, 2023) Krivenko, Pavel; Rudenko, Igor; Konstantynovskyi Oleksandr
    The application of alkali-activated slag cement concrete (hereinafter AASC concrete) is relevant for building constructions which are exploited in aggressive environments with exposed class XF4. It is due to increased freeze-thaw resistance of AASC concrete in water solutions of salts if compared with portland cement concrete. The aim of this work was to investigate the effects of technological factors on porous structure and freeze-thaw resistance of plasticized AASC concrete in NaCl solution. It was shown that increasing of fresh concrete consistency from class S1 up to class S4 due to plasticization by complex admixture “polyorganohydrosiloxane - sodium lignosufonate - polyethylene glycol” as well as application of alkaline component in dry form, in contrast to liquid form, ensures negative changes in porous structure of AASC concrete. These changes cause decreasing of freeze-thaw resistance from mark F500 down to F200. It was revealed that hardening of plasticized AASC concrete under normal conditions (t = 20±2 °С, RH = 95±5%), compared with hardening in water or under steam curing (t = 85±5 °С), ensures more effective porous structure which causes maintained freeze-thaw resistance of F300 in contrast to F200 and F250 agreeable. Effective technological decisions for advanced freeze-thaw resistant of AASC concrete were determined.