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  • Документ
    Feasibility of incorporating SO42--ions in zeolite-like matrices based on alkaline aluminosilicate binders
    (Elsevier BV, 2023-08) Krivenko, Pavlo; Rudenko, Igor; Konstantynovskyi, Oleksandr; Vaičiukynienė, Danutė
    Factors determining minimization of the influence of sulfate environments on concrete and risk of corrosion of embedded steel reinforcement have been analyzed. Coatings based on alkaline aluminosilicate binders were proposed to prevent transport of the sulfate ions into concrete. The formation of water resistant zeolite-like matrices on the alkaline aluminosilicate binder of the Na2O-K2O-Al2O3-SiO2-H2O system at 20 ± 2 ◦C can be provided by the use of calcium-containing modifying additives. Optimized molar ratios between oxides of binder constituent were SiO2/Al2O3 = 4–5 and K2O/(Na2O + K2O) = 0.15–0.30. The results of the study show that the speed of incorporating sulfate ions in cement matrix of binder from the sulfate environment is dependent upon a cation and ranks as follows: (NH4)2SO4 > MgSO4 > Na2SO4 > CaSO4. Complete protection of concrete against the penetration of sulfates can be reached when the developed coating is applied in a thickness of 3 mm.
  • Документ
    Study on physico-mechanical properties of the modified alkaline aluminosilicate adhesive-bonded timber elements
    (2019) Guzii, S.; Krivenko, P.; Bondarenko, O.; Kopylova, T.
    The purpose of the work was to study physico-mechanical properties of glued connections of wood rods, toothed lamellae after splicing and corner spike clamping of window frames which were obtained in the production conditions. The alkaline aluminosilicate binder-based adhesive (glue) of the composition 0.8Na2O·Al2O3·4.5SiO2·20H2O modified using organo-mineral additives was used in testing. After solidification of the adhesive, the samples were cut to determine the strength of frame corner joints in bending, glued timber connections for splitting along the grains, toothed glued connections in bending and water resistance of the glued connections of timber elements. The results of these tests showed high values of strength characteristics in case of the proposed modified alkaline aluminosilicate binder-based adhesive (glue), which were by 1.5 times higher than those in case of the WoodMax (D2) taken as a reference glue, and in water resistance complied with Class D2/D3 as per PN-EN 204.