Будівництво та цивільна інженерія
Постійний URI для цього зібранняhttps://repositary.knuba.edu.ua/handle/987654321/1219
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Документ Feasibility of incorporating SO42--ions in zeolite-like matrices based on alkaline aluminosilicate binders(Elsevier BV, 2023-08) Krivenko, Pavlo; Rudenko, Igor; Konstantynovskyi, Oleksandr; Vaičiukynienė, DanutėFactors determining minimization of the influence of sulfate environments on concrete and risk of corrosion of embedded steel reinforcement have been analyzed. Coatings based on alkaline aluminosilicate binders were proposed to prevent transport of the sulfate ions into concrete. The formation of water resistant zeolite-like matrices on the alkaline aluminosilicate binder of the Na2O-K2O-Al2O3-SiO2-H2O system at 20 ± 2 ◦C can be provided by the use of calcium-containing modifying additives. Optimized molar ratios between oxides of binder constituent were SiO2/Al2O3 = 4–5 and K2O/(Na2O + K2O) = 0.15–0.30. The results of the study show that the speed of incorporating sulfate ions in cement matrix of binder from the sulfate environment is dependent upon a cation and ranks as follows: (NH4)2SO4 > MgSO4 > Na2SO4 > CaSO4. Complete protection of concrete against the penetration of sulfates can be reached when the developed coating is applied in a thickness of 3 mm.Документ Effect of technological factors on freeze-thaw resistance of alkali-activated slag cement concrete in NaCl solution(AIP Publishing, 2023) Krivenko, Pavel; Rudenko, Igor; Konstantynovskyi OleksandrThe application of alkali-activated slag cement concrete (hereinafter AASC concrete) is relevant for building constructions which are exploited in aggressive environments with exposed class XF4. It is due to increased freeze-thaw resistance of AASC concrete in water solutions of salts if compared with portland cement concrete. The aim of this work was to investigate the effects of technological factors on porous structure and freeze-thaw resistance of plasticized AASC concrete in NaCl solution. It was shown that increasing of fresh concrete consistency from class S1 up to class S4 due to plasticization by complex admixture “polyorganohydrosiloxane - sodium lignosufonate - polyethylene glycol” as well as application of alkaline component in dry form, in contrast to liquid form, ensures negative changes in porous structure of AASC concrete. These changes cause decreasing of freeze-thaw resistance from mark F500 down to F200. It was revealed that hardening of plasticized AASC concrete under normal conditions (t = 20±2 °С, RH = 95±5%), compared with hardening in water or under steam curing (t = 85±5 °С), ensures more effective porous structure which causes maintained freeze-thaw resistance of F300 in contrast to F200 and F250 agreeable. Effective technological decisions for advanced freeze-thaw resistant of AASC concrete were determined.